Other types of fuels have been emulsified contain between 5 and 30% water (by mass) in the overall fuel emulsion. These emulsified fuels were recognized in Europe ( France and Italy) and CEN workshop standard was established (CWA 15145:2004). Oil continuous (water-in-oil) emulsified fuels are exemplified by diesel (or biodiesel blended fuels) and water emulsions. which have a calorific value and are used in industrial applications can also be converted to emulsified fuels, thus reducing the need to use cutter fluids and improving the combustion emissions associated with the inferior fuels. Water continuous emulsions of residual fuel, heavy fuel oils etc. Water continuous emulsions of very heavy crudes, bitumen are easier to pump than the original fuel, which would require considerable heating and / or dilution with a distilled product (kerosene or light crude) in order to make them easy to handle. These are often described as a high internal phase emulsion (HIPE) because the continuous phase is around 30% of the composition of the fuel, whereas it is more usual for the dispersed phase to be the minor component. Water continuous (oil-in-water) emulsified fuels are exemplified by the Orimulsion system and bitumen emulsions. Both use surfactants (also called emulsifiers) and can be either water-in-oil (invert emulsions), or oil-in-water (regular emulsions) or bicontinuous (also called multiple or complex emulsions). Microemulsions are isotropic whereas macroemulsions are prone to settling (or creaming) and changes in particle size over time. The essential differences between the two are stability (microemulsions are thermodynamically stable systems, whereas macroemulsions are kinetically stabilized) and particle size distribution (microemulsions are formed spontaneously and have dimensions of 10 to 200 nm, whereas macroemulsions are formed by a shearing process and have dimensions of 100 nm to over 1 micrometer). Emulsion fuels can be either a microemulsion or an ordinary emulsion (sometimes referred to as macroemulsion, to differentiate it from microemulsion). In the case of emulsions, both phases are the immiscible liquids, oil and water. The most commonly used emulsion fuel is water-in-diesel emulsion. Emulsions are a particular example of a dispersion comprising a continuous and a dispersed phase. Emulsified Fuels are emulsions composed of water and a combustible liquid, either oil or a fuel.
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